Reactions of Organostannanes Catalyzed by a Palladium-Iminophosphine Complex.

Theoretical study on the mechanism of hydromethoxylation catalyzed by palladium(II) complex

Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...

Theoretical study on the mechanism of hydromethoxylation catalyzed by palladium(II) complex

Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...

Suzuki cross-coupling reactions catalyzed by palladium complex of an inexpensive phosphinite, 2-diphenylphosphinoxynaphthyl

A facile and less expensive monophosphinite ligand 2-(diphenylphosphinoxy)-naphthyl, C H OPPh (1) has been synthesized from the reaction 10 7 2 f -naphthol with chlorodiphenylphosphine. The mixture of Pd(OAc)2 and 1 catalyzes the Suzuki cross-coupling of a variety of aryl halides with ryl boronic acids at room temperature or at 60 ◦C, giving generally high yields even under low catalytic loads....

Ionic Liquids: A Versatile Medium for Palladium-Catalyzed Reactions

Cross-coupling reactions of aryl and vinyl chlorides catalyzed by a palladium complex derived from an air-stable H-phosphonate.

A palladium complex derived from air-stable TADDOLP(O)H catalyzes efficiently Hiyama, Stille, Kumada and Suzuki cross-coupling reactions of aryl and vinyl chlorides.